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Eucheuma cottonii seaweed-based biochar for adsorption of methylene blue dye
Saeed, A.A.H.; Harun, N.Y.; Sufian, S.; Siyal, A.A.; Zulfiqar, M.; Bilad, M.R.; Vagananthan, A.; Al-Fakih, A.; Ghaleb, A.A.S.; Almahbashi, N. (2020). Eucheuma cottonii seaweed-based biochar for adsorption of methylene blue dye. Sustainability 12(24): 10318. https://dx.doi.org/10.3390/su122410318
In: Sustainability. MDPI: Basel. ISSN 2071-1050; e-ISSN 2071-1050, meer
Peer reviewed article  

Beschikbaar in  Auteurs 

Trefwoorden
    Seaweed
    Eucheuma cottonii Weber-van Bosse, 1913 [WoRMS]
    Marien/Kust
Author keywords
    biochar; pyrolysis; methylene blue; adsorption; seaweed

Auteurs  Top 
  • Saeed, A.A.H.
  • Harun, N.Y.
  • Sufian, S.
  • Siyal, A.A.
  • Zulfiqar, M.
  • Bilad, M.R.
  • Vagananthan, A.
  • Al-Fakih, A.
  • Ghaleb, A.A.S.
  • Almahbashi, N.

Abstract
    Pollution from dye containing wastewater leads to a variety of environmental problems, which can destroy plant life and eco-systems. This study reports development of a seaweed-based biochar as an adsorbent material for efficient adsorption of methylene blue (MB) dye from synthetic wastewater. The Eucheuma cottonii seaweed biochar was developed through pyrolysis using a tube furnace with N2 gas, and the properties were later improved by sulfuric acid treatment. The adsorption studies were conducted in a batch experimental setup under initial methylene blue concentrations of 50 to 200 mg/L, solution pH of 2 to 10, and temperature of 25 to 75 °C. The characterization results show that the developed biochar had a mesoporous pore morphology. The adsorbent possessed the surface area, pore size, and pore volume of 640 m2/g, 2.32 nm, and 0.54 cm3/g, respectively. An adsorption test for 200 mg/L of initial methylene blue at pH 4 showed the best performance. The adsorption data of the seaweed-based biochar followed the Langmuir isotherm adsorption model and the pseudo-second-order kinetic model, with the corresponding R2 of 0.994 and 0.995. The maximum adsorption capacity of methylene blue using the developed seaweed‑based biochar was 133.33 mg/g. The adsorption followed the chemisorption mechanism, which occurred via the formation of a monolayer of methylene blue dye on the seaweed-based biochar surface. The adsorption performance of the produced seaweed biochar is comparable to that of other commercial adsorbents, suggesting its potential for large-scale applications.

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